Intramolecular Cross-linking of Polymers Using Difunctional Acetylenes via Click Chemistry


Cengiz H., Aydogan B. , Ates S., Acikalin E., Yağcı Y.

DESIGNED MONOMERS AND POLYMERS, cilt.14, ss.69-78, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 14 Konu: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1163/138577210x541213
  • Dergi Adı: DESIGNED MONOMERS AND POLYMERS
  • Sayfa Sayısı: ss.69-78

Özet

An efficient approach was described for the intramolecular cross-linking of azide-functionalized poly(styrene-co-chloromethyl styrene) co-polymers (PS-N-3) via click chemistry at room temperature. Reaction of PS-N-3 with the appropriate diacetylene functional compounds such as 1,4-diethynylbenzene (DEB) and 1,10-dipropargyloxy decane (DPD) in ultra-dilute solutions led to unimolecular particle-like structures. The resulting polymers were characterized in detail by H-1-NMR, FT-IR, GPC and DSC measurements. (C) Koninklijke Brill NV, Leiden, 2011